Spectrophotometric Determination of Ni(II) Ion with 7Bromo-2-Nitroso-1-Oxinaphthalene-3,6-Disulphocid
Spectrophotometric Determination of Ni(II) Ion with 7Bromo-2-Nitroso-1-Oxinaphthalene-3,6-Disulphocid |
||
 |
 |
|
| © 2024 by IJETT Journal | ||
| Volume-72 Issue-6 |
||
| Year of Publication : 2024 | ||
| Author : Nazirov Sh.S., Turaev Kh.Kh., Kasimov Sh.A., Tillaev Kh. R, Alimnazarov B. Sh., Abdullaeva B.B |
||
| DOI : 10.14445/22315381/IJETT-V72I6P106 | ||
How to Cite?
Nazirov Sh.S., Turaev Kh.Kh., Kasimov Sh.A., Tillaev Kh. R, Alimnazarov B. Sh., Abdullaeva B.B, "Spectrophotometric Determination of Ni(II) Ion with 7Bromo-2-Nitroso-1-Oxinaphthalene-3,6-Disulphocid," International Journal of Engineering Trends and Technology, vol. 72, no. 6, pp. 57-63, 2024. Crossref, https://doi.org/10.14445/22315381/IJETT-V72I6P106
Abstract
In this article, the spectrophotometric detection method of complexing Ni(II) ion with 7-bromo-2-nitroso-1oxynaphthalene-3,6-disulfoacid (BNOX-S, S-3,6) (HR) with organic analytical reagent developed and studied optimal conditions: λmax = 640, pH = 6,5, universal buffer, reagent - buffer - Ni(II) - distilled water, BNOKS-S with 0.05% relative to TNi2+=10 μg/25ml, 1.0 ml of S-3.6 reagent was found to be sufficient. The area of obedience to the Bouguer-Lambert-Behr law was determined to be 1.0-17.5 μg/25 ml. Absorption spectra were studied: sensitivity, according to Sendel, was 0.0011 μg/cm2, contrast ∆λ = 100 nm. The composition of the complex and the mechanism of complex formation were studied using the Nazarenko method, isomolar series method, Asmus' straight-line method, and spectrophotometric titration methods. The molar ratio of the complex is Me: R=1:2. The actual molar extinction coefficient (εreal= 50000), the formation equilibrium constant (Kequilibrium = 9.71·10-5) of the complex formed by Ni(II) with BNOKS-S, S-3,6, the stability of the complex constant using the Babko method (lgβ = 18,87), the confidence interval of the deviation from the mean value (∆X = 0.104) and the lower limit of detection (Qminimum = 0.203 μg/25ml) were determined. The results of the graduated graph were mathematically processed using the method of small squares, and a linear mathematical equation was developed: Yi = 7,7·10-3 + 1,78·10-2Xi. The effect of foreign ions was studied. The developed method was used in an artificial mixture. In this case, the relative standard deviation (Sr) did not exceed 0.021.
Keywords
Ni(II) ion, 7-bromo-2-nitroso-1-oxynaphthalene-3,6-disulfoacid, Organic analytical reagent.
References
[1] Zuhair A.A. Khammas, and Hawraa M. Abdulkareem, “A New Visible Spectrophotometric Approach for Mutual Determination of Amoxicillin and Metoclopramide Hydrochloride in Pharmaceuticals after Cloud Point Extraction,” Science Journal of Analytical Chemistry, vol. 4, no. 5, pp. 66-76, 2016.
[CrossRef] [Google Scholar] [Publisher Link]
[2] S.M. Turabdzhanov, R.A. Tashkaraev, and B.Sh. Kedel’baev, “Hydrogenation of Benzene on Nickel Catalysts Promoted by Ferroalloys,” Theoretical Foundations of Chemical Engineering, vol. 47, no. 5, pp. 633-636, 2013.
[CrossRef] [Google Scholar] [Publisher Link]
[3] Anita Martinović-Bevanda, and Njegomir Radić, “Spectrophotometric Sequential Injection Determination of D-Penicillamine Based on a Complexation Reaction with Nickel Ion,” Analytical Sciences, vol. 29, pp. 669-671, 2013.
[CrossRef] [Google Scholar] [Publisher Link]
[4] Abbas Afkhami, Morteza Bahram, and Ali Reza Zarei, “Comparison of Partial Least Squares Regression and H-Point Standard Addition Method for Simultaneous Spectrophotometric Determination of Zinc, Cobalt and Nickel by 1-(2-Pyridylazo) 2-Naphthol in Micellar Media,” Microchimica Acta, vol. 148, pp. 317-326, 2004.
[CrossRef] [Google Scholar] [Publisher Link]
[5] Samata Badhe et al., “Stability Constants of Ni(II)- and Cu(II)-N-heterocycle Complexes According to Spectrophotometric Data,” Russian Journal of Physical Chemistry A, vol. 89, pp. 2254-2258, 2015.
[CrossRef] [Google Scholar] [Publisher Link]
[6] Jian Deng et al., “Cloud Point Extraction and Simultaneous Spectrophotometric Determination of V(V), Co(II) and Cu(II) Ions in Water Samples by 5-Br-PADAP Using Partial Least Squares Regression,” Journal of Radioanalytical and Nuclear Chemistry, vol. 300, pp. 835842, 2014.
[CrossRef] [Google Scholar] [Publisher Link]
[7] Nguyen Quoc Thang, and Le Van Tan, “Comparison of Two Preconcentration Methods for the Determination of Nickel Using a Ni–2-(2Thiazolylazo)-p-Cresol Complex: Extraction and Sorption onto Ion Exchange Resin,” Journal of Analytical Chemistry, vol. 77, pp. 14131418, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[8] Nomozov Abror Karim Ugli et al., “Salsola Oppositifolia Acid Extract as a Green Corrosion Inhibitor for Carbon Steel,” Indian Journal of Chemical Technology, vol. 30, no. 6, pp. 872-877, 2023.
[CrossRef] [Google Scholar] [Publisher Link]
[9] Y. Bazel’, M. Reclo, and J. Šandrejová, “Using a Switchable-Hydrophilicity Solvent for the Extraction-Spectrophotometric Determination of Nickel,” Journal of Analytical Chemistry, vol. 72, pp. 1018-1023, 2017.
[CrossRef] [Google Scholar] [Publisher Link]
[10] M.A. Shaymardanova et al., “Study of Process of Obtaining Monopotassium Phosphate Based On Monosodium Phosphate and Potassium Chloride,” Chemical Problems, vol. 3, no. 21, pp. 279-293, 2023.
[CrossRef] [Google Scholar] [Publisher Link]
[11] Berrin Topuz, and Ece Talya Altinişik, “Simultaneous Preconcentration and Determination of Cu(II), Ni(II), and Co(II) in Food and Environmental Samples by the Application of Chelate Adsorption on Amberlite XAD-1180,” Food Analytical Methods, vol. 16, pp. 1043– 1054, 2023.
[CrossRef] [Google Scholar] [Publisher Link]
[12] Mohanna Ezati et al., “A Continuous Sample Drop Flow-Based Microextraction Method for Spectrophotometric Determination of Cobalt with 1-(2-Pyridylazo)-2-Naphthol in Water Samples,” Journal of Analytical Chemistry, vol. 76, pp. 172–179, 2021.
[CrossRef] [Google Scholar] [Publisher Link]
[13] R. Agnihotri, A. Singh, and N. Agnihotri, “Extraction and Spectrophotometric Determination of Molybdenum(VI) Using 3-Hydroxy-2 7 [3-(4-Methoxyphenyl)-1-Phenyl-4-Pyrazolyl]-4-Oxo-4H-1-Benzopyran as a Chelating Agent,” Journal of Analytical Chemistry, vol. 74, pp. 81–86, 2019.
[CrossRef] [Google Scholar] [Publisher Link]
[14] Ali Reza Zarei, and Kobra Mardi, “Development of Spectrophotometric Method for Simultaneous Determination of Copper β-Resorcylate, Lead β-Resorcylate and Lead Oxide in Double Base Solid Propellants Using Mean Centering of Ratio Spectra Technique,” Journal of the Iranian Chemical Society, vol. 19, pp. 3347-3356, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[15] Yugao Guo et al., “Effective Enrichment and Simultaneous Quantitative Analysis of Trace Heavy Metal Ions Mixture in Aqueous Samples by the Combination of Radial Electric Focusing Solid Phase Extraction, UV-Vis Spectrophotometric Determination and Partial Least Squares Regression,” Water, Air, and Soil Pollution, vol. 228, 2017.
[CrossRef] [Google Scholar] [Publisher Link]
[16] Syed Najmul Hejaz Azmi et al., “Utility of Cefixime as a Complexing Reagent for the Determination of Ni(II) in Synthetic Mixture and Water Samples,” Environmental Monitoring and Assessment, vol. 185, pp. 4647–4657, 2013.
[CrossRef] [Google Scholar] [Publisher Link]
[17] Yasemin Çağlar, and Zekeriya Biyiklioglu, “Spectrophotometric Determination of Hg(II) in Water Samples by Dispersive Liquid Liquid Microextraction with Use Ionic Liquid after Derivatization with a Water Soluble Fe(II) Phthalocyanine,” Journal of Inclusion Phenomena and Macrocyclic Chemistry, vol. 90, pp. 331-339, 2018.
[CrossRef] [Google Scholar] [Publisher Link]