Double-Condensed Phosphates of Bivalent Metals and Ammonium: Obtain NH4PO3 from Solutions and its Research
Double-Condensed Phosphates of Bivalent Metals and Ammonium: Obtain NH4PO3 from Solutions and its Research |
||
|
||
© 2024 by IJETT Journal | ||
Volume-72 Issue-3 |
||
Year of Publication : 2024 | ||
Author : Umarov Sh. Sh, Turaev Kh. Kh, Kasimov Sh A, Kholboeva A. I, Muminova Sh. N., Begamov B. Kh |
||
DOI : 10.14445/22315381/IJETT-V72I3P114 |
How to Cite?
Umarov Sh. Sh, Turaev Kh. Kh, Kasimov Sh A, Kholboeva A. I, Muminova Sh. N., Begamov B. Kh, "Double-Condensed Phosphates of Bivalent Metals and Ammonium: Obtain NH4PO3 from Solutions and its Research," International Journal of Engineering Trends and Technology, vol. 72, no. 3, pp. 153-161, 2024. Crossref, https://doi.org/10.14445/22315381/IJETT-V72I3P114
Abstract
Despite the small share of nanoparticles in the field of chemistry, the demand for modifiers is increasing every day. This is due to their high physical, mechanical, and other mechanical properties, resistance to aggressive environments, and the ability to use them in a wide temperature range. According to the results of this study, the introduction of metal phosphates into the polymer improves the physical and mechanical properties of polyolefins. The physico-mechanical properties of the obtained polymer composite materials improved by 1-3 times compared to the initial polyamide-66 samples without filling. It is more important to produce polymer materials based on metal-containing compounds and to use them in practice. The inclusion of metal phosphates among fillers increases the fire resistance of composites. IR, thermal analysis, TG and DTA, DSK, Raman spectroscopy, X-ray diffraction, burning time, and oxygen index were also determined. As a result of the introduction of fillers, polymer molecules are connected with metal binders, and the elasticity, shock, fire resistance, and heat resistance of polymers have increased up to 3 times. The burning time is shortened, and the oxygen index is increased from 17% to 24%. At the same time, ammonium polyphosphate, an inorganic salt of phosphoric acid, was used as a filler, a widely used compound for the production of paints and varnishes with fire-resistant properties. These mineral fertilizers are high-molecular fire-resistant additives, the structure of which is formed as a result of combining monomeric orthophosphates into one polymer chain.
Keywords
Polyamide-66, polypropylene, ammonium polyphosphate, nickel oxide, cobalt oxide, zinc oxide, lead oxide, iron oxide.
References
[1] Mahtab Ahmad et al., “Biochar as a Sorbent for Contaminant Management in Soil and Water: A Review,” Chemosphere, vol. 99, pp. 19-33, 2014.
[CrossRef] [Google Scholar] [Publisher Link]
[2] A.F. Selevich et al., “Synthesis in the Ammonium Polyphosphate Melt and Thermal Behaviour of Binary Polyphosphates Mg(NH4)2(P03)4 and Ca(NH4)2(P03)4,” Phosphorus Research Bulletin, vol. 18, pp. 93-98, 2005.
[CrossRef] [Google Scholar] [Publisher Link]
[3] Anatoly Selevich et al., “Formation of Double Divalent Metal-Ammonium Condensed Phosphates in the NH4PO3 Melt,” Phosphorus Research Bulletin, vol. 19, pp. 228-233, 2005.
[CrossRef] [Google Scholar] [Publisher Link]
[4] Bing Wang et al., “Adsorption and Desorption of Ammonium by Maple Wood Biochar as a Function of Oxidation and pH,” Chemosphere, vol. 138, pp. 120-126, 2015.
[CrossRef] [Google Scholar] [Publisher Link]
[5] L.S. Ivashkevich et al., “Powder Diffraction Study of Ba(NH4)4(P03)6,” Acta Crystallographica Section E, vol. 63, no. 1, pp. 16-18, 2007.
[CrossRef] [Google Scholar] [Publisher Link]
[6] T.R. Aslamazova et al., “Modifying Latex Polymers by Using Highly Dispersed Iron Powder as a Filler,” Protection of Metals and Physical Chemistry of Surfaces, vol. 55, pp. 1091-1096, 2019.
[CrossRef] [Google Scholar] [Publisher Link]
[7] Dorota Dukarska, and Janina Łecka, “Optimization of the Process of Pressing Particleboards By Means of Modifying PhenolFormaldehyde Resin with Amide Polymers,” Wood as a Raw Material and Material, vol. 64, pp. 403-409, 2006.
[CrossRef] [Google Scholar] [Publisher Link]
[8] Maria Nowakowska, Krzysztof Szczubiałka, and Mirosław Grębosz, “Modifying the Thermosensitivity of Copolymers of Sodium Styrene Sulfonate and N-Isopropylacrylamide with Dodecyltrimethylammonium Chloride,” Colloid and Polymer Science, vol. 283, pp. 291-298, 2004.
[CrossRef] [Google Scholar] [Publisher Link]
[9] A. Yu. Teterina et al., “Developments in the Field of Biocompatible Composite Materials Based on Biopolymers and Calcium Phosphates Adapted to Prototyping Technology,” Polymer Science, Series D, vol. 14, pp. 265-268, 2021.
[CrossRef] [Google Scholar] [Publisher Link]
[10] Xueyang Zhang et al., “Ball Milling Biochar with Ammonia Hydroxide or Hydrogen Peroxide Enhances its Adsorption of Phenyl Volatile Organic Compounds (VOCs),” Journal of Hazardous Materials, vol. 403, 2021.
[CrossRef] [Google Scholar] [Publisher Link]
[11] S.E. Hale et al., “The Sorption and Desorption of Phosphate-P, Ammonium-N and Nitrate-N in Cacao Shell and Corn Cob Biochars, Chemosphere, vol. 91, pp. 1612-1619, 2013.
[CrossRef] [Google Scholar] [Publisher Link]
[12] Muhammad Bilal Shakoor, Zhi-Long Ye, and Shaohua Chen, “Engineered Biochars for Recovering Phosphate and Ammonium from Wastewater: A Review,” Science of the Total Environment, vol. 779, 2021.
[CrossRef] [Google Scholar] [Publisher Link]
[13] Zhanghong Wang et al., “Biochar Produced from Oak Sawdust by Lanthanum (La)-Involved Pyrolysis for Adsorption of Ammonium (NH4+), Nitrate (NO3−), and Phosphate (PO43−),” Chemosphere, vol. 119, pp. 646-653, 2015.
[CrossRef] [Google Scholar] [Publisher Link]
[14] F. Pantoja et al., “Removal of Ammonium and Phosphates from Aqueous Solutions by Biochar Produced from Agricultural Waste,” Journal of Material Cycles and Waste Management, vol. 25, pp. 1921-1934, 2023.
[CrossRef] [Google Scholar] [Publisher Link]
[15] M.A. Shaymardanova et al., “Study of Processe of Obtaining Monopotassium Phosphate Based on Monosodium Phosphate and Potassium Chloride,” Chemistry Problems, no. 3, pp. 279-293, 2023.
[CrossRef] [Google Scholar] [Publisher Link]
[16] Nomozov Abror Karim Ugli et al., “Salsola Oppositifolia Acid Extract as a Green Corrosion Inhibitor for Carbon Steel,” Indian Journal of Chemical Technology, vol. 30, no. 6, pp. 872-877, 2023.
[CrossRef] [Google Scholar] [Publisher Link]
[17] H.S. Beknazarov, and A.T. Dzhalilov, “Protection of Steel from Corrosion by Oligomeric Inhibitors and their Compositions,” Chemistry and Chemical Technology, vol. 47, no. 1, pp. 50-52, 2015.
[Google Scholar] [Publisher Link]