A Preliminary Study of Alkali-Activated Pozzolan Materials Produced with Sodium Hydroxide Activator
A Preliminary Study of Alkali-Activated Pozzolan Materials Produced with Sodium Hydroxide Activator |
||
|
||
© 2023 by IJETT Journal | ||
Volume-71 Issue-7 |
||
Year of Publication : 2023 | ||
Author : Parea R. Rangan, M. Tumpu, Mansyur, James Thoengsal |
||
DOI : 10.14445/22315381/IJETT-V71I7P236 |
How to Cite?
Parea R. Rangan, M. Tumpu, Mansyur, James Thoengsal, "A Preliminary Study of Alkali-Activated Pozzolan Materials Produced with Sodium Hydroxide Activator," International Journal of Engineering Trends and Technology, vol. 71, no. 7, pp. 375-382, 2023. Crossref, https://doi.org/10.14445/22315381/IJETT-V71I7P236
Abstract
Mortar that is more environmentally friendly (green mortar) is defined as concrete that at least uses waste material as one of its components or that does not cause environmental damage during the production process. Geopolymer is an environmentally friendly technology because it utilizes pozzolanic materials such as fly ash, rice straw ash, and laterite soil as waste materials. This work describes the experimental inquiry carried out to produce the geopolymer mortar based on alkali-activated fly ash, rice straw ash, and laterite soil by sodium hydroxide (NaOH). The influence of the curing technique on compressive strength and optimum mix proportion of geopolymer mortar were explored. In experiments, an alkaline activator (NaOH) was used with a binder composition at weight ratios of 4.17:1.67:4.17, rice straw ash, fly ash, and laterite soil were combined. To examine the workability and mechanical properties of the final geopolymer, experiments on mortar flow and compressive strength were performed. Fresh geopolymers subjected to flow testing reveal that all components are tightly linked, and segregation does not occur. The hardened test specimen was treated in two different ways—in the open air and by being submerged in water solutions—for up to 7 and 28 days, respectively, to ascertain its resistance. The 12 M alkali-activated geopolymer mortar may reach compressive strengths of 1.72 N/mm2 and 3.22 N/mm2 for air curing and 1.63 N/mm2 and 1.68 N/mm2 for water curing, respectively, after 7 and 28 days of casting when cured for 24 hours. The compressive strength was shown to rise with an increase in curing method, curing time, and alkali activator concentration.
Keywords
Fly ash, Rice straw ash, Laterite soil, Sodium hydroxide, Geopolymer.
References
[1] M. Tumpu, and D.S. Mabui, “Effect of Hydrated Lime (Ca(OH)2) to Compressive Strength of Geopolymer Concrete,” AIP Conference Proceedings, vol. 2391, no. 1, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[2] Mansyur, and M. Tumpu, “Compressive Strength of Normal Concrete Using Local Fine Aggregate from Binang River in Bombana district, Indonesia,” AIP Conference Proceedings, vol. 2391, no. 1, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[3] Parea Rusan Rangan, and M. Tumpu, “Influence of Coconut Shell Ash and Lime towards CBR Value and Subgrade Bearing Capacity,” AIP Conference Proceedings, vol. 2391, no. 1, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[4] Mansyur, and M. Tumpu, “Compressive Strength of Non-Sand Concrete with Coarse Aggregate in Kolaka District as Yard Pavement,” AIP Conference Proceedings, vol. 2391, no. 1, 2022.
[CrossRef] [Google Scholar] [Publisher Link]
[5] Parea R. Rangan et al., “Characteristics of Geopolymer using Rice Straw Ash, Fly Ash and Laterite Soil as Eco-friendly Materials,” International Journal of GEOMATE, vol. 19, no. 73, pp. 77-81, 2020.
[Google Scholar] [Publisher Link]
[6] M.B. Ali, R. Saidur, and M.S. Hossain, “A Review on Emission Analysis in Cement Industries,” Renewable and Sustainable Energy Reviews, vol. 15, no. 5, pp. 2252-2261, 2011.
[CrossRef] [Google Scholar] [Publisher Link]
[7] Rosmariani Arifuddin et al., “Study of Measuring the Application of Construction Safety Management Systems (CSMS) in Indonesia using the Analytic Hierarchy Process,” International Journal of Engineering Trends and Technology this Link is Disabled, vol. 71, no. 3, pp. 354-361, 2023.
[CrossRef] [Publisher Link]
[8] Xiaolu Guo, Huisheng Shi, and Warren A. Dick, “Compressive Strength and Microstructural Characteristics of Class C Fly Ash Geopolymer,” Cement and Concrete Composites, vol. 32, no. 2, pp. 142–147, 2010.
[CrossRef] [Google Scholar] [Publisher Link]
[9] P.R. Rangan et al., “Compressive Strength of High-strength Concrete with Cornice Adhesive as a Partial Replacement for Cement,” IOP Conference Series: Earth and Environmental Science, vol. 871, 2021.
[CrossRef] [Google Scholar] [Publisher Link]
[10] C.D. Atis et al., “Very High Strength (120 MPa) Class F fly Ash Geopolymer Mortar Activated at Different NaOH Amount, Heat Curing Temperature and Heat Curing Duration,” Construction and Buildding Materials, vol. 96, pp. 673–678, 2015.
[CrossRef] [Google Scholar] [Publisher Link]
[11] P.R. Rangan et al., “Strength Performance of Sodium Hydroxide-activated Fly Ash Rice Straw Ash and Laterite Soil Geopolymer Mortar,” IOP Conferences Series: Earth and Environmental Science, vol. 473, 2020.
[CrossRef] [Google Scholar] [Publisher Link]
[12] Rusdi U. Latief et al., “Labor Productivity Study in Construction Projects Viewed from Influence Factors,” Civil Engineering Journal, vol. 9, no. 3, 2023.
[CrossRef] [Google Scholar] [Publisher Link]
[13] National Standardization Body, Indonesian National Standard (SNI) 1974-2011 Method of Concrete Compressive Strength Test with Cylindrical Test Objects, Jakarta: National Standardization Council (in Indonesia), 2011.
[14] Chung-Ho Huang et al., “Mix Proportions and Mechanical Properties of Concrete Containing Very High-volume of Class F fly Ash,” Construction and Building Materials, vol. 46, pp. 71–78, 2013.
[CrossRef] [Google Scholar] [Publisher Link]
[15] Alexandre Silva De Vargas et al., “The Effect of Na2O/SiO2 Molar Ratio, Curing Temperature and Age on Compressive Strength, Morphology and Microstructure of Alkali-Activated Fly Ash-Based Geopolymers,” Cement & Concrete Composites, vol. 33, no. 6, pp. 653-660, 2011.
[CrossRef] [Google Scholar] [Publisher Link]
[16] Parea Rusan Rangan, M. Tumpu, and Mansyur, “Marshall Characteristics of Quicklime and Portland Composite Cement (PCC) as Fillers in Asphalt Concrete Binder Course (AC-BC) Mixture,” Annals of Chemistry: Science of Materials, vol. 47, no. 1, pp. 51-55, 2023.
[CrossRef] [Google Scholar] [Publisher Link]
[17] Thomas Omollo Ofwa, David Otieno Koteng, and John Nyiro Mwero, “Evaluating Superplasticizer Compatibility in the Production of High Performance Concrete using Portland Pozzolana Cement CEM II/B-P,” SSRG International Journal of Civil Engineering, vol. 7, no. 6, pp. 92-100, 2020.
[CrossRef] [Publisher Link]
[18] J.G.S. van Jaarsveld, J.S.J. van Deventer, and G.C. Lukey, “The Characterization of Source Materials in Fly Ash-based Geopolymers,” Materials Letters, vol. 57, no. 7, pp. 1272–1280, 2003.
[CrossRef] [Google Scholar] [Publisher Link]
[19] Herman Parung et al., “Crack Pattern of Lightweight Concrete under Compression and Tensile Test,” Annals of Chemistry: Science of Materials, vol. 47, no. 1, pp. 35-41, 2023.
[Google Scholar] [Publisher Link]
[20] R. Maignien, Review of Research on Laterite, National Academies Sciences Engineering Medicine, 1966.
[Google Scholar] [Publisher Link]
[21] ASTM C618-03, Standard Specification for Coal Fly Ash and Raw or Calcined Natural Pozzolan for Use in Concrete, 2003.
[22] ASTM C 618-05, Standard Specification for Coal Fly Ash and Raw or Calcined Natural Pozzolan for Use in Concrete, 2005.
[23] Josefa Rosello et al., “Rice Straw ash: A Potential Pozzolanic Supplementary Material for Cementing Systems,” Industrial Crops and Products, vol. 103, pp. 39-50, 2017.
[CrossRef] [Google Scholar] [Publisher Link]
[24] Chaosheng Tang et al., “Strength and Mechanical Behavior of Short Polypropylene Fiber Reinforced and Cement Stabilized Clayey Soil,” Geotextiles and Geomembranes, vol. 25, no. 194–202, 2007.
[CrossRef] [Google Scholar] [Publisher Link]
[25] A.K. Kasthurba, Manu Santhanam, and M.S. Mathew, “Investigation of Laterite Stones for Building Purpose from Malabar region, Kerala state, SW India — Part 1: Field Studies and Profile Characterisation,” Construction and Building Materials, vol. 21, no. 1, pp. 73–82, 2007.
[CrossRef] [Google Scholar] [Publisher Link]
[26] N. Krishna Raju, and R. Ramakrishnan, “Properties of Laterite Aggregate Concrete,” Materials and Construction, vol. 5, pp. 307–314, 1972.
[CrossRef] [Google Scholar] [Publisher Link]
[27] D. Adepegba, “Comparative Study of Normal Concrete which Contains Laterite Fines Instead of Sand,” Building Science, vol. 10, no. 2, pp. 135–141, 1975.
[CrossRef] [Google Scholar] [Publisher Link]
[28] Fola Lasisi, J.A. Osunade, and A.O. Adewale, “Short Term Studies on the Durability of Laterized Concrete and Laterite-Cement Mortar,” Building and Environment, vol. 25, no. 1, pp. 77-83, 1990.
[CrossRef] [Google Scholar] [Publisher Link]
[29] J.I. Arimanwa, and S. Sule, “Prediction of Cost of Chikoko-Cement Concrete Using Osadebe’s Regression Polynomial,” International Journal of Recent Engineering Science, vol. 6, no. 3, pp. 9-18, 2019.
[CrossRef] [Google Scholar] [Publisher Link]
[30] M.A. Salau, and L.A. Balogun, “Shear Resistance of Reinforced Laterised Concrete Beams without Shear Reinforcement,” Building and Environment, vol. 25, no. 1, pp. 71-76, 1990.
[CrossRef] [Google Scholar] [Publisher Link]
[31] L.O. Ettu et al., “The Suitability of Using Laterite as Sole Fine Aggregate in Structural Concrete,” International Journal of Scientific and Engineering Research, vol. 4, no. 5, pp. 502-507, 2013.
[Google Scholar] [Publisher Link]
[32] National Standardization Body, Indonesian National Standard (SNI) 03-6825-2002 Method of Testing the Compressive Strength of Portland Cement Mortar for Civil Works. Jakarta: National Standardization Council, 2002.
[33] J. Temuujin, A. Van Riessen, and R. Williams, “Influence of Calcium Compounds on the Mechanical Properties of Fly Ash Geopolymer Pastes,” Journal of Hazardous Materials, vol. 167, no. 1-3, pp. 82-88, 2009.
[CrossRef] [Google Scholar] [Publisher Link]
[34] P. Priyadharshini, K. Ramamurthy, and R.G. Robinson, “Excavated Soil Waste as Fine Aggregate in Fly Ash Based Geopolymer Mortar,” Applied Clay Science, vol. 146, pp. 81-91, 2017.
[CrossRef] [Google Scholar] [Publisher Link]
[35] Saysunee Jumrat, Burachat Chatveera, and Phadungsak Rattanadecho, “Dielectric Properties and Temperature Profile of Fly Ash-based Geopolymer Mortar,” International Communications in Heat and Mass Transfer, vol. 38, no. 2, pp. 242-248, 2011.
[CrossRef] [Google Scholar] [Publisher Link]
[36] P.V. Rambabu, and G.V Rama Rao, “Study on Sugarcane Bagasse Ash as a Partial Replacement of Cement in M60 Grade Concrete Exposed to Acidic Environment,” SSRG International Journal of Civil Engineering, vol. 4, no. 9, pp. 1-9, 2017.
[CrossRef] [Publisher Link]
[37] Djwantoro Hardjito, and B. Vijaya Rangan, “Development and Properties of Low-Calcium Fly Ash-Based Geopolymer Concrete,” Curtin University Technology: Perth, Australia, 2005.
[Google Scholar] [Publisher Link]
[38] Mo Bing-hui et al., “Effect of Curing Temperature on Geopolymerization of Metakaolin-based Geopolymers,” Applied Clay Science, vol. 99, pp. 144–148, 2014.
[CrossRef] [Google Scholar] [Publisher Link]
[39] G.L. Oyekan, “Impact Resistance of Laterised Concrete,” Journal of Science and Technology, vol. 24, no. 1, 2004.
[Google Scholar] [Publisher Link]
[40] P. Chindaprasirt, and W. Chalee, “Effect of Sodium Hydroxide Concentration on Chloride Penetration and Steel Corrosion of Fly Ash-based Geopolymer Concrete under Marine Site,” Construction and Building Materials, vol. 63, pp. 303 – 310, 2014.
[CrossRef] [Google Scholar] [Publisher Link]