IJBTT

Synthesis and Research of Sorbent Based on Sodium Metalsilicate and Thiourea

Synthesis and Research of Sorbent Based on Sodium Metalsilicate and Thiourea
	© 2022 by IJETT Journal
	Volume-70 Issue-11
	Year of Publication : 2022
	Authors : Turaev Kh, Gafforova Sh., Dzhalilov A, Sottikulov E, Soatov S
	DOI : 10.14445/22315381/IJETT-V70I11P210

How to Cite?

Turaev Kh, Gafforova Sh., Dzhalilov A, Sottikulov E, Soatov S, "Synthesis and Research of Sorbent Based on Sodium Metalsilicate and Thiourea," International Journal of Engineering Trends and Technology, vol. 70, no. 11, pp. 99-105, 2022. Crossref, https://doi.org/10.14445/22315381/IJETT-V70I11P210

Abstract
The purpose of this study is to synthesize and research a new type of sorbent based on thiourea and sodium metasilicate, which has a wide range of applications and has selective sorption properties due to the presence of the thio group in the molecule and the presence of silicon in its composition. During the synthesis of the sorbent, 60 g of thiourea and 100 g of sodium metasilicate were taken from an aqueous solution and heated in a water bath at a temperature of 90 °C. The duration of the reaction is 25-30 minutes, after 30 minutes the reaction mass cools down to room temperature, and after 24 hours the mass comes to a brittle state in the form of a gel. The resulting mass was crushed to a size of 1 mm and thermally treated at a temperature of 200 °C. The synthesized sorbent was thoroughly washed in distilled water and stored at 105°С-110°С until the mass reached a constant state. The yield of the reaction product is 91%. The reaction mechanism of the organ hybrid sorbent based on thiourea and sodium metasilicate was compared and the IR-spectra of the initial reagents and the obtained product were analyzed and the reaction mechanism was proposed. At the same time, the results of the thermal analysis of the obtained sorbent and SEM analysis of the sorbent were presented.

Keywords
Corbent, Thiomochevine, Sodium metasilicate, IR spectrum, Thermogravimetric curve, Mass loss, Scanning electron microscopy.

Reference
[1] Kuperstokh, V.L. Classification of Ordered Objects / V.L. Kuperstokh, V.A. Trofimov , “Algorithms of Statistical Information Processing: Sat. Art. - Novosibirsk: Science. Sib. Department, pp. 88–89, 1974.
[2] A.G. Morozova, T.M. Lonzinger, V.A. Skotnikov, J.N. Sahu, G.G. Mikhailov, J.L. Schenk, A. Bhattacharyya and Y. Kapelyushin, “Utilization of Metallurgical Slag with Presence of Novel Cao-Mgo-Sio2-Al2O3 as a Composite Sorbent for Wastewater Treatment Contaminated By Cerium,” Journal of Cleaner Production, vol. 255, pp. 120286, 2020. Crossref, https://doi.org/10.1016/j.jclepro.2020.120286
[3] Ostanov U.Y., Beknazarov K.S and Dzhalilov A.T, “ Study By Differential Thermal Analysis and Thermogravimetric Analysis of the Heat Stability of Polyethylene Stabilised With Gossypol Derivatives,” International Polymer Science and Technology, vol. 38, no. 9, pp. 25–27, 2011. Crossref, https://doi.org/10.1177/0307174X1103800906
[4] Nurilloev Zafar, Beknazarov Khasan and Nomozov Abror, "Production of Corrosion Inhibitors Based on Crotonaldehyde and Their Inhibitory Properties," International Journal of Engineering Trends and Technology, vol. 70, no. 8, pp. 423-434, 2022. Crossref, https://doi.org/10.14445/22315381/IJETT-V70I8P243
[5] Abdelmonaim Azzouz, Suresh Kumar Kailasa, Sang Soo Lee, Andrés J. Rascón, Evaristo Ballesteros, Ming Zhang and Ki-Hyun Kim, “Review of Nanomaterials As Sorbents in Solid-Phase Extraction for Environmental Samples,” Trac Trends in Analytical Chemistry, vol. 108, pp. 347-369, 20180. Crossref, https://doi.org/10.1016/J.Trac.2018.08.009
[6] Ibrahim M. El-Naggar and Mamdouh M. Abou-Mesalam, “Novel Inorganic Ion Exchange Materials Based on Silicates; Synthesis, Structure and Analytical Applications of Magneso-Silicate and Magnesium Alumino-Silicate Sorbents,” Journal of Hazardous Materials, vol. 149, no. 3, pp. 686-692, 2007. Crossref, https://doi.org/10.1016/J.Jhazmat.2007.04.029
[7] J.S.Hadi and A.A.Abudl Kareem, "Thermogravimetric Study of Some Schiff Base Metal Complexes," SSRG International Journal of Applied Chemistry, vol. 7, no. 1, pp. 34-44, 2020. Crossref, https://doi.org/10.14445/23939133/IJAC-V7I1P108
[8] V.V. Tomina, N.V. Stolyarchuk, I.V. Melnyk, Yu L. Zub, T.F. Kouznetsova, V.G. Prozorovich and A.I. Ivanets, “Composite Sorbents Based on Porous Ceramic Substrate and Hybrid Amino- and Mercapto-Silica Materials for Ni(II) and Pb(II) Ions Removal,” Separation and Purification Technology, vol. 175, pp. 391-398, 2017. Crossref, https://doi.org/10.1016/j.seppur.2016.11.040
[9] Turaev Kh.Kh., Ermuratova N.A and Eshkurbonov F.B, “Study of the Ion-Exchange Capacity of Sulfur- and Nitrogen-Containing Anion Exchangers Using the Titrimetric Method of Analysis,” Universum: Technical Sciences: Electron. Scientific Journal, no. 4, 2019. URL: http://7universum.com/ru/tech/archive/item/7161
[10] Srinivas Seemala and Ludwig Peetz, "Investigation of Thermal Properties and Mechanical Strength of Polymer: Introducing Silicon Carbide (SIC) and Salt (NACL) Nano Particles Into Poly Styrene," SSRG International Journal of Polymer and Textile Engineering, vol. 9, no. 2, pp. 1-7, 2022. Crossref, https://doi.org/10.14445/23942592/IJPTE-V9I2P101
[11] Mohamed E. Mahmoud, Mohamed F. Amira, Amal A. Zaghloul and Ghada A.A. Ibrahim, “Microwave-Enforced Sorption of Heavy Metals from Aqueous Solutions on the Surface of Magnetic Iron Oxide-Functionalized-3-Aminopropyltriethoxysilane,” Chemical Engineering Journal, vol. 293, pp. 200-206, 2016. Crossref, https://doi.org/10.1016/J.Cej.2016.02.056
[12] Michaela Tokarčíková, Jana Seidlerová, Oldřich Motyka, Ondřej Životský, Klára Drobíková and Roman Gabor, “Experimental Verification of Regenerable Magnetically Modified Montmorillonite and Its Application for Heavy Metals Removal From Metallurgical Waste Leachates,” Journal of Water Process Engineering, vol. 39, pp. 101691, 2021. Crossref, https://doi.org/10.1016/j.jwpe.2020.101691
[13] Kuroda, K., Shimojima, A., Kawahara, K., Wakabayashi, R., Tamura, Y., Asakura, Y and Kitahara, M, “Utilization of Alkoxysilyl Groups for the Creation of Structurally Controlled Siloxanebased Nanomaterials (Review),” Chemistry of Materials, vol. 26, no. 1, pp. 211–220, 2014. Crossref, https://doi.org/10.1021/cm4023387
[14] Murata S., Hata H., Kimura T., Sugahara Y and Kuroda K, “Effective Adsorption of Chlorophyll A By FSM-Type Mesoporous Silica Modified With 1,4-Butanediol, Langmuir, vol. 16, no. 18, pp. 7106–7108, 2000. Crossref, https://doi.org/10.1021/la991393m
[15] Murata S., Hata H., Kimura T., Sugahara Y and Kuroda K, “Effective Adsorption of Chlorophyll A By FSM-Type Mesoporous Silica Modified With 1,4-Butanediol, Langmuir, vol. 16, no. 18, pp. 7106–7108, 2000. Crossref, https://doi.org/10.1021/la991393m
[16] Enric Pellicer-Castell, Carolina Belenguer-Sapiña, Pedro Amorós, Jamal El Haskouri, José Manuel Herrero-Martínez and Adela Mauri-Aucejo, “Study of Silica-Structured Materials as Sorbents for Organophosphorus Pesticides Determination in Environmental Water Samples,” Talanta, vol. 189, pp. 560-567, 2017. Crossref, https://doi.org/10.1016/J.Talanta.2018.07.044
[17] Narzullaev A.X, Beknazarov X.S, Jalilov A.T and Rajabova M.F, “Studying the Efficiency of Corrosion Inhibitor IKTSF-1, IR-DEA, IR-DAR-20 in 1m Hcl,” International Journal of Advanced Science and Technology , vol. 28, no. 15, pp. 113–122. Available At:. http://sersc.org/journals/index.php/IJAST/article/view/1555
[18] Beknazarov K.S and Dzhalilov A.T, “The Synthesis of Oligomeric Derivatives of Gossypol and the Study of their Antioxidative Properties,” International Polymer Science and Technology. vol. 43, no. 3, pp.T25–T30. Crossref, https://doi.org/10.1177/0307174X1604300305
[19] Hamoud, F., Ramsh, S.M., Fundamenskii, V.S, Gurzhii, V.V., Brusina, M.A., Arikhipova, N.G., Sedunova, P.A., Medvedskii, N.L and khrabrova, E.S., “Reaction of Thiourea With Formaldehyde and Simplest Aliphatic Diamines,” Russian Journal of Organic Chemistry, vol. 52, pp. 121–126, 2016. Crossref, https://doi.org/10.1134/S1070428016010231
[20] A.G. Morozova, T.M. Lonzinger, V.A. Skotnikov, J.N. Sahu, G.G. Mikhailov, J.L. Schenk, A. Bhattacharyya and Y. Kapelyushin, “Utilization of Metallurgical Slag With Presence of Novel Cao-Mgo-Sio2-Al2O3 As A Composite Sorbent for Wastewater Treatment Contaminated By Cerium,” Journal of Cleaner Production, vol. 255, pp. 120286, 2020. Crossref, https://doi.org/10.1016/j.jclepro.2020.120286
[21] Plaza, L., Castellote, M., Nevshupa, R and Jimenez-Relinque, E., “High-Capacity Adsorbents From Stainless Steel Slag for the Control of Dye Pollutants in Water,” Environmental Science and Pollution Research, vol. 28, pp. 23896–23910, 2021. Crossref, https://doi.org/10.1007/S11356-020-12174-0
[22] Łukasz J. Wilk, Agnieszka Ciechanowska and Elżbieta Kociołek-Balawejder, “Removal of Sulfides From Water Using a Hybrid Ion Exchanger Containing Manganese(IV) Oxide,” Separation and Purification Technology, vol. 231, pp. 115882, 2020. Crossref, https://doi.org/10.1016/J.Seppur.2019.115882
[23] Dongjiang Yang, Blain Paul, Wujun Xu, Yong Yuan, Erming Liu, Xuebin Ke, Robert M. Wellard, Cheng Guo, Yao Xu, Yuhan Sun and Huaiyong Zhu, “Alumina Nanofibers Grafted With Functional Groups: A New Design Inefficient Sorbents for Removal of Toxic Contaminants from Water,” Water Research, vol. 44, no. 3, pp. 741-750, 2010. Crossref, https://doi.org/10.1016/j.watres.2009.10.014